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gallium phosphate : ウィキペディア英語版 | gallium phosphate
Gallium phosphate (GaPO4 or gallium orthophosphate) is a colorless trigonal crystal with a hardness of 5.5 on the Mohs scale. GaPO4 is isotypic with quartz, possessing very similar properties, but the silicon atoms are alternately substituted with gallium and phosphorus, thereby doubling the piezoelectric effect. GaPO4 has many advantages over quartz for technical applications, like a higher electromechanical coupling coefficient in resonators, due to this doubling. Contrary to quartz, GaPO4 is not found in nature. Therefore, a hydrothermal process must be used to synthesize the crystal. ==Modifications== GaPO4 possesses, in contrast to quartz, no α-β phase transition, thus the low temperature structure (structure like α-quartz) of GaPO4 is stable up to 970°C, as are most of its other physical properties. Around 970°C another phase transition occurs which changes the low quartz structure into another structure similar with cristobalite.
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